This study investigated the characteristics of mercury emitted from a largescale coalfired power plant in Taiwan via intensive sampling campaigns. The air pollution control devices equipped in this coalfired power plant include selective catalytic reduction, fabric filter and seawater flue gas desulfurization. During three sampling campaigns, mercury concentrations emitted from this large ...
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Abstract. Most coal requires some preparation before use. Preparation may range from simply crushing to provide a size consist suitable for certain types of boilers to extensive size reduction and cleaning to remove sulfur and ashforming mineral matter. At present, coal cleaning is accomplished through physical separation of particles low in ...
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The coal hydrogen production process requires hightemperature steam as a reactant. Coalfired boilers are usually used to provide hightemperature steam. The ammoniabased desulphurization process is an effective technology to remove SO2 in the coalfired flue gas. However, the mass transfer coefficient of SO2 in such an engineered process is not readily available in the literature. In this ...
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Flue gas desulfurization (FGD) systems using lime or limestone as the chemical reagent are widely used throughout the world for SO 2 emissions control at coalfired power plants. Ammoniabased ...
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In addition, the sulfur content of the raw coal reduces from % to %, total desulfurization rate of %, whose organic sulfur desulfurization is % after coal in shake flask experiments. And the desulfurization rate approaches the maximum value on the tenth day (from Figure 2B). It was demonstrated that strain SX12 could ...
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Since the "Eleventh FiveYear Plan" period, the construction of flue gas desulfurization and denitrification facilities for coalfired power plants have been accelerated to control the emissions of sulfur dioxide (SO 2) and nitrogen oxides (NO X) and thus to address the issue of acid rain in to the goal of the "Thirteenth FiveYear Plan for Energy Saving and Emission ...
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Physical desulfurization methods can only remove inorganic sulfur and are economical and practical in nature. 14,15 Highgradient magnetic separation technology is an effective method for physical desulfurization, which can be used to deal with fine particles of paramagnetic minerals and is applied to the desulfurization of fine coal (mainly ...
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Flotation desulfurization is the process of separating sulfur from coal samples into tailing products based on the differences in the physical and chemical properties of the mineral surfaces without changing the original sulfur content of the entire coal. ... and {111} facets in alk. soln., which is beneficial to the coal desulfurization. These ...
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The complicated mass transfer during coke making process leads to the uneven spatial distribution of sulfur forms in coke, which is of great importance for the sulfur transformation and desulfurization efficiency. ... Char yield and desulfurization rate of YJH coal during pyrolysis. Fig. 5 presents the release rate of H 2 S, SO 2, ...
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Flue gas desulfurization (FGD) processes have been widely used since the early 1970's for control of sulfur dioxide emissions from coalfired power plants. First generation FGD systems employ ''wet processes'' whereby the flue gas is contacted with a solution or slurry of an alkali reagent. Most of these installations use either lime or limestone.
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The resultant products of this process,, (NH 4) 2 SO 4, can be recycled as fertilizers while reducing the discharge of solid or liquid waste. During the desulfurization process, many elements produced from the burned coal, such as metal ions, ash, fluoride, and chloride, are absorbed and accumulated in the desulfurization slurry.
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Fluegas desulfurization (FGD) material is a product of a process typically used for reducing SO 2 emissions from the exhaust gas system of a coalfired boiler. The physical nature of these materials varies from a wet sludge to a dry, powdered material depending on the process.
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The major coal desulphurization technologies prior to combustion are physical coal cleaning, chemical and biological methods. Each has some technical and economical limitations. Physical coal cleaning can only remove limited amount of inorganic sulphur due to insufficient liberation.
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environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. This work summarizes the desulfurization and denitration ... In the wet desulfurization process, the scaling and blockage of equipment are easy to occur in the process site. In view of the above problems, a calciumsodium ...
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Before and after the desulfurization process; total sulfur, pyritic sulfur, carbon content and calorific value were measured. The highest removal efficiencies of total sulfur and pyritic sulfur for Burdur coal obtained as 41% and 67%, for Tunçbilek coal obtained as 41% and 35%, and for Ermenek coal obtained as 47% and 41%, respectively.
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The desulfurization process took place at a pH of 35, the coalparticle size was 7545 μm, the pulp density was 5%, the temperature was 35°C, and the incubation time was 8 h. Chemical studies also revealed a decrease in the ash content and an increase in the calorific value of coal from 6219 cal/g to 6406 and 6315 cal/g, which indicated ...
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Abstract To explore the feasibility of organic sulfur removal using organic acids, oxalic acid, citric acid and ascorbic acid were selected as desulfurization reagents. Combined with microwave irradiation technology, desulfurization experiments of highsulfur coal treated with nitric acid were conducted. The orthogonal experimental results showed that the microwave synergistic citric acid ...
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To solve the safety problem of spontaneous combustion of highsulfur coal, applied microbiology, physical chemistry, reaction kinetics theory, combined with the SEM, FTIR and TGDTGDSC experiments and analysis of testing methods, the microbial desulfurization experiments were carried out, and the change law of the desulfurization reaction of coal before and after the element composition, main ...
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XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave heating and conventional heating conditions. The effects of microwave fields on the molecular properties, bond strength and reaction kinetic of organic sulfurcontaining groups were studied by quantum chemical calculation.
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For future approaches, as well as desulfurization process, increasing the purity of coal may also promote the value of coal and prevent environment pollution. In the study of Etemadifar et al., growing and resting cells of heterotrophic Rhodococcus erythropolis strains PD1, R1, and FMF, and R. qingshengii were utilized in sulfur removal and ...
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XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave heating and conventional heating conditions. The effects of microwave fields on the molecular properties, bond strength and reaction kinetic of organic sulfurcontaining groups were studied by quantum chemical calculation.
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Desulfurization systems in coalfired power stations often suffer the problem of high operating costs caused by a ruleofthumb control strategy, which implies great potential for optimization of the operation. ... In this paper, an operation strategy optimization method for the desulfurization process is proposed based on a data mining ...
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The desulfurization process of circulating fluidized bed desulfurization technology involves the injection of flue gas from the bottom of the fluidized bed through a Venturi tube. ... Microwave heating motivated performance promotion and kinetic study of iron oxide sorbent for coal gas desulfurization. Fuel, 267 (2020), Article 117215, ...
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The flue gas desulfurization solids in the dry process (DFGDS) are the newly formed CaSO 4 and the unreacted excess of CaO. They are carried along with the coal FA out of the boiler, forming the end product (FA + DFGDS), which is highly alkaline due to the excess of CaO with respect to the initial SO 2 (Ca:S = ). Due to a low ...
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At present, the desulfurization technology is divided into pretreatment, inuse treatment, and posttreatment. Inuse treatment, in the case of coal, is generally defined as the spraying of desulfurizer into the coalburning boiler, which is capable of converting SO 2 and SO 3 emissions from coal combustion into sulfites or sulfates (Lu et al. 1998; Sun et al. 2018).
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Desulfurization of Coal by Pyrolysis and Hydropyrolysis with Addition of KOH/NaOH Quanrun Liu, Haoquan Hu, Shengwei Zhu, Qiang Zhou, Wenying Li, Xianyong Wei, and Kechang Xie View Author Information Cite this: Energy Fuels 2005, 19, 4, Publication Date: April 23, 2005 https:////ef
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Coal desulfurization is imperative to create clean coal and reducing harmful emissions during the combustion process. However, organic sulfur in coal is more difficult to remove than inorganic sulfur. Therefore, in this paper, a method of coal sample desulfurization using citric acid with microwave assisted was proposed, and experimental ...
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In coal combustion, to generate electric power and process heat, the sulfur is emitted as SO2, which is seen as one of the main causes of acid rain. This effect has led to an interest in the three main methods of removing coal sulfur: coal cleaning, inbed desulfurization, and flue gas desulfurization. Coal cleaning includes physical, chemical,
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Abstract. Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Due to its abundance, chemical and physical properties, FGDG has been used in several beneficial applications. However, during the past decade, the rate of beneficially used FGDG has ...
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Mechanism of Pyrite Microbial Desulfurization. The oxidation process of coal conversion is possible by microorganisms after getting influenced by the polyfunctional coal structure and this process usually depends on two main factors: size or shape of coal and surface properties of microorganisms (Konishi et al. 1990). The morphology and ...
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Most of the coal, oil and natural gas produced in the world are used as fuels and a small part is used as a chemical feedstock. Undesulfurized coal and oil in the combustion process will produce a large number of sulfur oxides (SOx), serious harm to human health, and environmental damage. The unpurified natural gas containing hydrogen sulfide (H2S) is difficult for industrial application. This ...
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Fluegas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide (SO 2) ... into exhaust ducts to eliminate SO 2 and SO 3 from process emissions. For a typical coalfired power station, fluegas desulfurization (FGD) may remove 90 per cent or more of the SO 2 in the flue gases.
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A large amount of SOx will be produced in the combustion process of coal without desulfurization, which is the main factor causing air pollution, environmental damage and increase.
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A material supplier from Belgium would like to produce limestone powder for his custome...
India is rich in various mineral resources and it is an important mineral processing market
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